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Field name	Details
Dewey Class	620.192 (DDC 22)
Title	Functional Materials and Biomaterials ([Ebook]) / with contributions by X. Dong Liu... [et al.]
Added Personal Name	Liu, X. Dong (Xiang Dong)
Added Personal Name	Abe, A.
Other name(s)	SpringerLink (Online service)
Publication	Berlin, Heidelberg : Springer-Verlag , 2007
Physical Details	: v.: digital
Series	Advances in polymer science 0065-3195 ; 209
ISBN	9783540715092
Summary Note	Hyperbranched polymers have emerged as a new class of macromolecules that show architectural beauty and multifaceted functionality of d- drimers while enjoying the ease of being prepared by simple, sing- step reaction procedures. A number of strategies have been developed for the synthesis of hyperbranched polymers. The commonly adopted - proach is self-condensation polymerization of AB -type monomers with x x?2 where A and B are mutually reactive functional groups, dating back to the theoretical work of Flory in the early 1950s [1]. Because of the limited commercial availability and dif?cult synthetic access to multifu- tional monomers bearing multiple, mutually reactive groups, alternative approaches suchas copolymerizations ofA monomers with B comonomers 2 x (x?3) have been developed [2 7]. Other polymerization reactions including self-condensing vinyl polymerizations initiated by cationic [8] and radical catalysts [9,10] and ring-opening multibranching polymerizations [11 15] have been explored, mainly for the synthesis of non-conjugated hyp- branched polymers [16 18]. Hyperbranched macromolecules have been constructed from various functional groups, among which, carbon-carbon triple-bond functionality uniquely stands out because it offers ready access to hyperbranched conju- tive macromolecules. Being unsaturated, it accommodates various addition reactions. In comparison to vinyl and alkyl protons, the acetylenic proton is most acidic (pK = 26; cf., pK =45forethyleneandpK = 62 for ethane), a a a thus enabling facile substitution and coupling reactions.":
System details note	Online access to this digital book is restricted to subscription institutions through IP address (only for SISSA internal users)
Internet Site	http://dx.doi.org/10.1007/978-3-540-71509-2
Links to Related Works	Subject References: Biochemistry . Biomedical materials . Chemistry and Materials Science . Medicinal Chemistry . Pharmacy . Polymer Sciences . Polymers . Authors: Abe, A. . Liu, X. Dong (Xiang Dong) . Corporate Authors: SpringerLink (Online service) . Series: Advances in polymer science . Classification: 620.192 (DDC 22) .

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Functional Materials and Biomaterials

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