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Functional Materials and Biomaterials
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Dewey Class
620.192 (DDC 22)
Titel
Functional Materials and Biomaterials ([Ebook]) / with contributions by X. Dong Liu... [et al.]
Added Personal Name
Liu, X. Dong (Xiang Dong)
Abe, A.
Other name(s)
SpringerLink (Online service)
Veröffentl
Berlin, Heidelberg : Springer-Verlag , 2007
Physical Details
: v.: digital
Reihe
Advances in polymer science
0065-3195 ; 209
ISBN
9783540715092
Summary Note
Hyperbranched polymers have emerged as a new class of macromolecules that show architectural beauty and multifaceted functionality of d- drimers while enjoying the ease of being prepared by simple, sing- step reaction procedures. A number of strategies have been developed for the synthesis of hyperbranched polymers. The commonly adopted - proach is self-condensation polymerization of AB -type monomers with x x?2 where A and B are mutually reactive functional groups, dating back to the theoretical work of Flory in the early 1950s [1]. Because of the limited commercial availability and dif?cult synthetic access to multifu- tional monomers bearing multiple, mutually reactive groups, alternative approaches suchas copolymerizations ofA monomers with B comonomers 2 x (x?3) have been developed [2 7]. Other polymerization reactions including self-condensing vinyl polymerizations initiated by cationic [8] and radical catalysts [9,10] and ring-opening multibranching polymerizations [11 15] have been explored, mainly for the synthesis of non-conjugated hyp- branched polymers [16 18]. Hyperbranched macromolecules have been constructed from various functional groups, among which, carbon-carbon triple-bond functionality uniquely stands out because it offers ready access to hyperbranched conju- tive macromolecules. Being unsaturated, it accommodates various addition reactions. In comparison to vinyl and alkyl protons, the acetylenic proton is most acidic (pK = 26; cf., pK =45forethyleneandpK = 62 for ethane), a a a thus enabling facile substitution and coupling reactions.":
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Online access to this digital book is restricted to subscription institutions through IP address (only for SISSA internal users)
Internet Site
http://dx.doi.org/10.1007/978-3-540-71509-2
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Schlagwörter:
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Biochemistry
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Biomedical materials
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Chemistry and Materials Science
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Medicinal Chemistry
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Pharmacy
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Polymer Sciences
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Polymers
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Authors:
Abe, A.
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Liu, X. Dong (Xiang Dong)
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SpringerLink (Online service)
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Advances in polymer science
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620.192 (DDC 22)
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